Safranin O dye removal using Senna fistula activated biomass: Kinetic, equilibrium and thermodynamic studies

Authors

  • C. J. Ajaelu Industrial Chemistry Programme, College of Agriculture, Engineering and Science, Bowen University, Iwo, Nigeria
  • O. Oyedele Industrial Chemistry Programme, College of Agriculture, Engineering and Science, Bowen University, Iwo, Nigeria
  • A. A. Ikotun Industrial Chemistry Programme, College of Agriculture, Engineering and Science, Bowen University, Iwo, Nigeria
  • E. O. Faboro Industrial Chemistry Programme, College of Agriculture, Engineering and Science, Bowen University, Iwo, Nigeria

Keywords:

Senna fistula, Safranin O, adsorbent, kinetics, thermodynamics

Abstract

The availability of potable water has decreased in recent times due to the extensive discharge of effluents from some industries. This contaminated water poses a great danger to both human and aquatic life. Senna fistula was activated using phosphoric acid, H3PO4 and its ability to remove Safranin O from aqueous solution was investigated. The characterization of Senna fistula activated carbon was done by Scanning Electron Microscopy and Fourier Transform Infrared Spectroscopy. The impacts of pH, initial dye concentration, contact time, and effect of temperature were investigated. Results showed that the optimum pH for the removal of Safranin O was 4.4. The adsorption capacity increased as the initial dye concentration increased from 30 - 130 mg/L. The dye adsorption equilibrium data were properly fitted to both Freundlich and Langmuir isotherms. The maximum uptake capacity for Safranin O was 22.1 mg/g. The kinetic studies indicated rapid sorption dynamics via a second-order kinetic model. The thermodynamic parameter shows that the sorption of Safranin O on Senna fistula activated carbon was feasible, spontaneous and endothermic. Senna fistula-activated carbon was found to be cheap and efficient adsorbents for the removal of Safranin O dye from aqueous solutions.

Dimensions

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Published

2022-12-22

How to Cite

Safranin O dye removal using Senna fistula activated biomass: Kinetic, equilibrium and thermodynamic studies. (2022). Journal of the Nigerian Society of Physical Sciences, 5(1), 951. https://doi.org/10.46481/jnsps.2023.951

Issue

Volume 5, Issue 1, February 2023

Section

Original Research
Copyright & Licensing

Copyright (c) 2022 C. J. Ajaelu, A. A. Ikotun, E. O. Faboro

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

Safranin O dye removal using Senna fistula activated biomass: Kinetic, equilibrium and thermodynamic studies. (2022). Journal of the Nigerian Society of Physical Sciences, 5(1), 951. https://doi.org/10.46481/jnsps.2023.951